Aqueous microdroplets containing only ketones or aldehydes undergo Dakin and Baeyer–Villiger reactions
نویسندگان
چکیده
منابع مشابه
Exchange Reactions of Aldehydes and Ketones
Using intra-red spectre,copy, the equilibriull ~xcMnge times have been determined tor a aeri•• of keton••, aromatio aldehyde" and a-keto.sters re8ctin~ with oxYaen 18 enriched water. Theso exchange tilMs have been ev.luated in terma ot ateria and electronic coneideration., and applIed to • ,Uacus.ion of the exohange ti"e. of ohlorophyll. a and b and ohlorophyll derlvativeao Introduction This in...
متن کاملReactions of Aldehydes and Ketones and their Derivatives
Formation and Reactions of Acetals and Related Species . . . . . . . . . . . . . . 1 Reactions of Glucosides and Nucleosides . . . . . . . . . . . . . . . . . . . . . . . . . 4 Reactions of Ketenes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Formation and Reactions of Nitrogen Derivatives . . . . . . . . . . . . . . . . . . . 7 Imines . . . . . . . . . . . . ...
متن کاملMagnesium-catalysed hydroboration of aldehydes and ketones.
The heteroleptic magnesium alkyl complex [CH{C(Me)NAr}(2)Mg(n)Bu] (Ar = 2,6-(i)Pr(2)C(6)H(3)) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.
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The formal intramolecular photoredox reaction initially discovered for the parent 2-(hydroxymethyl)anthraquinone (1) in aqueous solution has been extended to a variety of anthraquinones derivatives 6-13, to explore the generality of the reaction, and to investigate its potential utility as a photodeprotecting chromophore. In addition, the related diketone 14 was studied to investigate the need ...
متن کاملSecondary organic aerosol formation by heterogeneous reactions of aldehydes and ketones: a quantum mechanical study.
Experimental studies have provided convincing evidence that aerosol-phase heterogeneous chemical reactions (possibly acid-catalyzed) are involved to some extent in the formation of secondary organic aerosol (SOA). We present a stepwise procedure to determine physical properties such as heats of formation, standard entropies, Gibbs free energies of formation, and solvation energies from quantum ...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2019
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c9sc05112k